1val = '<s>'
2idx = [val] + df.index.drop(val).tolist()
3print (idx)
4['<s>', 'noun', 'verb', 'Adj', '<end>']
5
6print (df.reindex(idx))
7
8 col1 col2 col3
9index
10<s> 9 6 5
11noun 1 1 1
12verb 4 6 1
13Adj 5 1 3
14<end> 0 0 0
15